CHAPTER 1:
CHEMICAL
REACTIONS AND EQUATIONS
Chemical
Change: It is a change in which one or more new substances are
formed. In a chemical change –
- New substances are formed
- Change in mass
- Changes in involved energy
- Some permanent change may also takes place
Chemical
Reaction: Chemical reactions are the chemical changes that results
in the formation of a new substance. Following observations helps us to
determine whether a chemical reaction has taken place-
- Change in state
- Change in colour
- Evolution of gas
- Change in temperature
What happens when
magnesium ribbon is burnt?
When magnesium ribbon burns in
air, it burns with a dazzling white flame and changes into a white powder. This
powder is magnesium oxide.
What will you observe
when lead nitrate solution is added in potassium iodide solution?
When both the solution mixes,
the lead particles and iodide particles combine and create two new compounds, a
yellow solid called lead iodide and white solid called potassium nitrate.
Pb(NO3)2 + 2KI → PbI2
+ 2KNO3
What happens when
zinc granules are added in the dilute hydrochloric acid or sulphuric acid?
By the action of dilute
sulphuric acid on zinc, hydrogen gas is released with the formation of zinc
chloride.
How can we determine that whether a chemical reaction takes place or
not?
Following observations helps us
to determine whether a chemical reaction has taken place-
- ·
Change in state
- ·
Change in colour
- ·
Evolution of gas
- ·
Change in
temperature
Chemical
Equations: The description of a chemical reaction in a sentence form
is quite long. It can be written in a shorter form, the simplest way to do this
is to write it in the form of a word equation. This word equation is known as
chemical equation.
Reactant:
The substances that undergo chemical changes in the reaction are the
reactants.
Product:
The new substance that is formed during the reaction is known as product.
Balanced
Chemical Equations: A balanced chemical equation is the one in which
the total mass of the elements present in the products of a chemical reaction
has to be equal to the total mass of the elements present in reactants.
How to balance chemical equation:
Let us try to balance following equation –
Fe +
H2O → Fe3O4 + H2
(i)Count the number of atoms of different elements
|
Element
|
No. of atoms in reactant
|
No. of atom in product
|
|
Fe
|
1
|
3
|
|
H
|
2
|
2
|
|
O
|
1
|
4
|
(ii)Start balancing with the compound that contains maximum
no. of atoms, it may be reactant or product. We select Fe3O4
and element oxygen in it.
|
Element
|
No. of atoms in reactant
|
No. of atom in product
|
|
Fe
|
1
|
3
|
|
H
|
2
|
2
|
|
O
|
1 X 4 = 4
|
4
|
Fe +
4H2O →
Fe3O4 + H2
(iii)Now let’s balance hydrogen atoms
|
Element
|
No. of atoms in reactant
|
No. of atom in product
|
|
Fe
|
1
|
3
|
|
H
|
8
|
2 X 4 = 8
|
|
O
|
4
|
4
|
Fe +
4H2O → Fe3O4 + 4H2
(iv)Now we have to balance Fe
|
Element
|
No. of atoms in reactant
|
No. of atom in product
|
|
Fe
|
1 X 3 = 3
|
3
|
|
H
|
8
|
8
|
|
O
|
4
|
4
|
Types of chemical reactions:
(1)
COMBINATION
REACTION: The chemical reaction in which a single product is formed
from two or more reactants is known as a combination reaction.
For example
(i) C + O2 →
CO2
(ii) 2H2
+ O2 → H2O
(iii) CaO + H2O →
Ca(OH)2 + Heat
(2) DECOMPOSITION REACTION: The
chemical reaction in which a single reactant breaks down to give simple
products is known as decomposition reaction.
For example
(i)
2FeSO4
→ Fe2O3 + SO2(g) + SO3(g)
(ii)
+
v
Decomposition of calcium carbonate to calcium
oxide and carbon dioxide on heating is an important decomposition reaction used
in various industries. Calcium oxide is called lime or quick lime, it is used
in the manufacture of cement.
v
When decomposition is carried out by heating, it
is called thermal decomposition. The reactions given in examples above are
thermal decomposition reactions.
(3) DISPLACEMENT REACTION: The
chemical reaction in which an element of a compound displaces or remove another
element is known as displacement reaction.
For example
(i)
Fe + CuSO4 → FeSO4 + Cu
(ii)
Zn
+ CuSO4 →
ZnSO4 + Cu
(iii)
Pb +
CuCl2 → PbCl2 + Cu
(4) DOUBLE DISPLACEMENT REACTION:
The chemical reaction in which there is an exchange of ions between the
reactants are called double displacement reaction.
For example
(i)
Na2SO4 +
BaCl2 → BaSO4 +
2NaCl
In this reaction SO42- and Ba2+ ions
exchange between the reactants.
(5) OXIDATION AND REDUCTION: The
chemical reaction in which if a substance gains oxygen or loses hydrogen during
a reaction, it is oxidised and if a substance loses oxygen or gains hydrogen
during a reaction, it is reduced.
For example
(i)
Oxidation :
2Cu + O2 → 2CuO
(ii)
Reduction : CuO +
H2 → Cu
+ H2O
v
REDOX REACTION: When one reactant gets oxidised
while the other gets reduced during a reaction. Such reactions are called
oxidation reduction reactions or redox reactions.
What will happen by
the reaction of calcium oxide with water?
By the reaction of calcium oxide
with water, formation of slaked lime occurs.
CaO + H2O → Ca(OH)2 {SLAKED LIME}
v
Slaked lime is used
for white washing the walls. Calcium hydroxide or slaked lime reacts slowly
with the carbon dioxide in air to form a thin layer of calcium carbonate on the
walls. Calcium carbonate is formed after two to three days of white washing and
gives a shiny finish to the walls.
Ca(OH)2 + CO2 → CaCO3 + H20
EXOTHERMIC
REACTION: Reaction in which heat is released along with the
formation of products are called exothermic reaction.
ENDOTHERMIC
REACTION: Reaction in which heat is absorbed for the formation of
products are called endothermic reaction.
Is respiration an
endothermic reaction or exothermic reaction?
Respiration is an exothermic
reaction because in the process of respiration, energy is released. As we need
energy to stay alive, we get this energy from the food we eat. During
digestion, food is broken down into simpler substances. For example, the food
that contain carbohydrates are broken down to form glucose. This glucose
combines with oxygen in the cells of our body and provides energy.
C6H12O6 + 6O2
→ 6CO2 + 6H2O +
ENERGY
RUSTING OF IRON: Iron
articles are shiny when new, but get coated with a reddish brown powder when
left alone for some time. This process is known as rusting of iron.
CORROSION: When a
metal is attacked by substances around it such as moisture, acids etc. it is
said to corrode and this process is called corrosion.
For
example: black coating on silver, green coating on copper.
RANCIDITY: Food turns
rancid when the fats and oils within them get oxidised and the taste and smell
of the food changes. Oxidation of fats generates highly reactive molecule in
the ramcid food which is responsible for the unpleasant odour and flavour.
PREVENTION FROM
CORROSION:
- Painting the metal surface.
- Powder coating of the surfaces.
- Oiling the metal.
- Galvanization: it is the process of applying a protective zinc coating to iron or steel articles, to prevent them from rusting.
PREVENTION
FROM RANCIDITY:
- Adding antioxidants (substances which prevent oxidation) to food.
- Storing food in airtight containers to slow the process of rancidification.
- Refrigerating food also helps to slow down rancidification.
- Replacing oxygen in the containers with another gas. For example, to prevent chips from turning rancid, chips manufacturers flush the bags with nitrogen gas.

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